Publications | Srinivas dharavath

Publications from IIT Kanpur

67."Employing the trifluoromethyl group on 5/5 fused triazolo[4,3-b][1,2,4]triazole backbone: a viable strategy for attaining balanced energetics". Sonali K.† ; Abhishek K.Y.† ; Sagar N.; Srinivas D*. Org. Lett., 2024. (Just accepted)
(Sonali K. and Abhishek K. Y. contributed equally to this work.)

66."Skeletal Editing of Energetic Materials: Acid-Catalyzed One-Step Synthesis of Bridged Triazoles High Energy Density Materials via Nef Reaction" Shreyasi B.‡, Navaneet K.‡, Vikas D. G, Srinivas D*. ACS Appl. Mater. Interfaces, 2024, 16(47), 64929-64939.
(Shreyasi B. and Navaneet K. contributed equally to this work).

65."Advancing Energetic Chemistry: First Synthesis of Sulfur-Based C-C Bonded Thiadiazole-Pyrazine Compounds with Nitrimino Moiety" Parasar K., Vikas D. G, Srinivas D*. Dalton trans., 2024, (Just accepted).

58. "One step synthesis of nitrogen-rich green primary explosives from secondary: synthesis, characterization, and performance study" Parasar K.; Vikas D. G; Srinivas D*. Mater. Adv., 2024, 5, 6399 - 6404.

57. "Single step synthesis of gem-dinitro methyl-1,2,4-triazole and its hydroxylamine salt: an alternative to the FOX-7 and other benchmark explosives" Parasar K.; Vikas D. G; Srinivas D*. Organic letters, 2024, 26 (22), 4788–4792.

56. "Elevating the energetic capabilities of metal coordination compounds by incorporating nitrate anions" Abhishek K. Y.†; Richa R.†; Srinivas D*. Dalton trans., 2024, 53, 10093-10098.
(Abhishek K. Y. and Richa R. contributed equally to this work.)

55. "Elaborating NH Bridged Nitrogen-Rich Energetic Materials via Base-Mediated Dimroth Rearrangement: Synthesis, Characterisation and Performance Study" Manojkumar J., Vikas D. G., Srinivas D.* J. Org. Chem., 2024, 89 (11), 8192–8200.

54. "Solvent free Potassium 3,5-dinitro-6-oxo-1,6-dihydropyrazin-2-olate 3D EMOF as thermally stable energetic material" Abhishek K. Y.; Vikas D. G; Srinivas D*. Chem. Asian J., 2024 (DOI: 10.1002/asia.202400409)

53. "Highly Dense N–N-Bridged Dinitramino Bistriazole-Based 3D Metal-Organic Frameworks with Balanced Outstanding Energetic Performance" Richa R.,‡ Navaneet K.,‡ Vikas D. G., Srinivas D.* ACS Appl. Mater. Interfaces, 2024, 16 (16), 20670–20680.
(Richa R. and Navaneet K. contributed equally to this work)

52. "Mixed- Metallic Energetic Metal-Organic Framework : New Structure Motif for Potential Heat-Resistant Energetic Materials" Richa R., Parasar K., Srinivas D.* Cryst. Growth Des., 2024, 24 (5), 2142–2148.

51. "Bistriazolotriazole-tetramine: commendable energetic moiety and cation" Rimpi D., Kalpana S., Vikas D. G.,* Srinivas D. J. Mol. Model., 2024, 30, 98.

This paper cover artwork is published on the inside front cover page for Issue 24, Page 10023 to 10362.

59. "Exploring the Explosive Potential: Synthesis and Characterization of Ring-Fused Oxadiazolo[3,4-b]pyrazine 1-Oxide Polymorphs with Balanced Energetic Properties" Abhishek K.Y.; Rimpi D.; Vikas D. G; Srinivas D*. Organic letters, 2024, 26(28), 6006–6011.

60. "Symmetric Refunctionalization of Diaminodinitropyrazine with Hydrazine and Aminotetrazole: Strategy to Enhancing Detonation Performance and Safety in Energetic Materials" Abhishek K.Y.†; Sonali K.†; Sagar N.; Vikas D. G; Srinivas D*. Inorg. Chem., 2024, 63(32), 15144–15153.
(Abhishek K. Y. and Sonali K. contributed equally to this work.)

62. "Trailblazing 3D MOFs Featuring 1,2,4-Dinitrimino Triazole: Redefining Energetic Materials and Iodine Encapsulation" Manojkumar J.; Richa R.; Srinivas D*. Adv. Funct. Mater., 2024, 2412638.

61. "Synthesis of C-C bonded Trifluoromethyl based High Energy Density Materials via ANRORC Mechanism" Parasar K.; Ramling S. M.; Vikas D. G.; Srinivas D*. Dalton trans., 2024, 53, 15324-15329.
(Parasar K. and Ramling S.M. contributed equally to this work)

64. "Synthesis and Performance Evaluation of Zwitterionic C-N Bonded Triazole-Tetrazole Based Primary Explosives" Shreyasi B., Vikas D. G, Srinivas D*. J. Org. Chem. 2024, 89 (19), 14038–14049.

50. "Zwitterionic fused pyrazolo-triazole based high performing energetic materials" Parasar K.,‡ Navaneet K.,‡ Vikas D. G., Srinivas D.* Chemical communications, 2024, 60, 1646-1649.
(Parasar K. and Navaneet K. contributed equally to this work)

49. "Amine and nitramine functionalization of imidazole-triazine and triazole-triazine skeletons: Exploring for potential multipurpose energetic materials" Abhishek K. Y.,‡ Manojkumar J.,‡ Vikas D. G., Srinivas D.* J. Heterocycl. Chem., 2024, 61 (3), 401-406. (Special issue)
(Abhishek K.Y. and Manojkumar J. contributed equally to this work.)

48. "Synthesis of advanced pyrazole and N-N bridged bistriazole-based secondary high energy materials" Abhishek K. Y.,‡ Navaneet K.,‡ Vikas D. G, Srinivas D*. Organic letters, 2023, 25 (48), 8606–8610.
(Abhishek K. Y. and Navaneet K. contributed equally to this work.)

47. "Azo-bridged Triazole Macrocycles: Computational Design, Energy Content, Performance and Stability Assessment" Kalpana S.; Anjali M.; Vikas D. G,* Srinivas D. Journal of Physical Chemistry A, 2023. 127(48), 10128–10138.

46. "Functionalization of fused imidazole-oxadiazole, triazole-oxadiazole and tetrazole-oxadiazole skeletons: search for stable and potential energetic materials" Rimpi D.; Anjali M.; Vikas D. G , Srinivas D. Comput Theor Chem , 2023, 1229, 114352

45. "Straightforward synthesis of insensitive 2-(1-hydroxy-2,2-dinitrovinyl)guanidine and its guanidinium dinitromethanide (GDNM) salt as a high energy density material" Abhishek K. Y.; Vikas D. G; Srinivas D*. J. Org. Chem., 2023. 88, 13178–13183.

44. "Energetic coordination compounds: self-assembled from the nitrogen-rich energetic C-C bonded pyrazole and triazole" Abhishek K. Y.†; Richa R.†; Vikas D. G; Srinivas D*. Dalton trans, 2023. 52, 12271-12281. (Abhishek K. Y. and Richa R. contributed equally to this work.)

43. "Computational Manifestation of Nitro Substituted Tris(triazole): Understanding the Impact of Isomerism on Performance- Stability Parameters" Anjali M.; Vikas D. G*; Srinivas D. The Journal of Physical Chemistry A, 2023, 127, 31, 6467–6475

42. "Poly tetrazole containing thermally stable and insensitive alkali metals-based 3D energetic Metal-Organic Frameworks (EMOFs)" Richa R., Parasar K., Vikas D. G. Srinivas D*. Inorganic Chemistry, 2023, 62(21), 8389–8396.

41. "Design and computational studies on energetic compounds composing bridged bis triazolo-triazine framework" Anjali M.; Rimpi D.; Vikas D. G*. Srinivas D. Chemical Physics, 2023. 571,111939.

40. "Synthesis, characterization, testing, and detonation performance studies of fused pyrazole-based fluorescent energetic materials" Shreyasi. B., Vikas D. G. Srinivas D* Materials Chemistry and Physics. 2023, 301, 127678.

39. "High-performing, insensitive and thermally stable energetic materials from zwitterionic gem-dinitromethyl substituted C-C bonded 1,2,4-triazole and 1,3,4-oxadi a zole" Abhish ek K. Y., Manojkumar. J., Vikas D. G. Srinivas D * Chemical communications.2023 , 59, 4324-4327.
(selected among the "top 60 Most Popular Articles of 2023" for the 60th anniversary edition of 2024)

63. "Elucidation of the influence of trinitro-diazinotriazine isomerism on the energetic properties and stability: Insights from DFT approach." Kalpana S., Rimpi D., Vikas D. G*, Srinivas D. Comput. Theor. Chem. 2024, 1241, 114931.

38. "Thermally stable and insensitive energetic cocrystals comprising nitrobarbituric acid coformer" Abhishek K. Y. , Vikas D. G. Srinivas D* Cryst. Growth Des. 2023, 23, 4, 2826–2836.

37. "Facile synthesis of thermally stable tetrazolo[1,5-b][1,2,4]triazine substituted energetic materials: Synthesis and characterization" Parasar K., Vikas D. G. Srinivas D* Dalton trans., 2023, 52, 747-753.

36. "Promising thermally stable energetic materials with the combination of pyrazole-1,3,4-oxadiazole and pyrazole-1,2,4-triazole backbones: facile synthesis and energetic performance" Abhishek K. Y. , Vikas D. G. Srinivas D* ACS Appl. Mater. Interfaces, 2022, 14, 44, 49898-49908

35. "Facile synthesis of nitroamino-1,3,4-oxadiazole with azo linkage: a new family of high-performance and biosafe energetic materials" Shreyasi B.,† Pradeep K.,† Vikas D. G., Shweta K., Dharmaraja A., and Srinivas D.* J. Mater. Chem. A, 2022. 10, 22803 - 22811. (Shreyasi B., Pradeep K. are equally contributed in this work)

34. "Computational Evaluation of Polycyclic Bis-oxadiazolo-pyrazine Backbone in Designing Potential Energetic Materials" Anjali Maan, Vikas D. G. Srinivas D. Polycyclic Aromatic Compounds, 2022. 43, 6717-6729 .

33. "Facile fabrication of functionalized pyrimidine derivatives: Constructing a new family of high performance and less sensitive Energetic compound" Abhishek K. Y. , Vikas D. G. Srinivas D*. J. Mater. Chem. A, 2022, 10, 12702-12712

32. "1,3,5-Tris[(2H‑tetrazol-5-yl)methyl]isocyanurate and Its Tricationic Salts as Thermostable and Insensitive Energetic Materials" Parasar K., Vikas D. G. Srinivas D*. Organic letters 2022, 24 (19), 3555–3559

31. "Potential energetic salts of 5,5′-methylenedi(4H-1,2,4-triazole-3,4-diamine) cation: Synthesis, characterization and detonation performance" Mathpati R. S., Abhishek K. Y., Vikas D. G. Srinivas D*. Energetic Materials Frontiers. 2022, 3(2), 90-96

30. "Unexpected Synthesis of Oxadiazole Analogues: Characterization and Energetic Properties" Abhishek K. Y., Parasar K., Vikas D. G. Srinivas D*. Asian J. Org. Chem., 2022, 11, e2021007 (Invited article)

29. "Computational assessment of nitrogen-enriched, stable and insensitive tris(1,2,4,5-tetrazin-3-yl)amine building block for energetic applications" Anjali Maan, Vikas D. G. Srinivas D*. Energetic Materials Frontiers. 2022, 3(1), 47–52

28. "Unfolding the chemistry of FOX-7: Unique energetic material and precursor with numerous possibilities" Shreyasi B., Abhishek K. Y., Parasar K., Vikas D. G. Srinivas D*. Chemical Engineering Journal, 2022, 431(4), 133378.

27. “Dianionic Nitrogen-rich Triazole and Tetrazole-Based Energetic Salts: Synthesis and Detonation Performance” Abhishek K. Y, Vikas G. D, Srinivas D*. Mater. Chem. Front., 2021, 5, 8352-8360.

26. “Tetranitro-diazinodiazines as high energy materials: computational investigation of structural aspects of fused heterocyclicbackbone and isomerism” Maan. A, Vikas G. D, Srinivas D. Structural Chemistry, 2021, 32, 2175–2181.

25. “Effect of Multiple Oxadiazole Rings with Nitro and Nitramino Functionalities on Energetic Properties: Computational Analysis of Structure-Property Relationship” Maan. A, Mathpati R. S., Vikas G. D, Srinivas D*. New J. Chem, 2021, 45, 7368-7376.

24. “Nitrogen-rich Compounds with Multiple Azole Rings: Gas Generant, Enthalpy Enhancer and Applicable Cationic Component” Mathpati R. S., Vikas G. D, Srinivas D*. Asian J. Org. Chem., 2021, 10, 421-427.

23. “Design, synthesis and investigations of a series of energetic salts through the variation of amines and concentration of picrate-anion” Mathpati R. S., Srinivas D., Nikhil K., Vikas G. D, Avijit K. P. and Ram K. T. Cryst Eng Comm, 2020, 22, 4842-4852.

Publications from Ph.D and Postdoc

22. "Use of Vinyl Sulfides in Fischer Indole Reactions" Parul P, Meghan F, Srinivas D, Jarrod W J, and Jakob M. Synthesis. 2022, 54 (22), 4917-4931. DOI: 10.1055/a-1868-4148.

21. “ Aldehyde to Ketone Homologation Enabled by Improved Access to Thioalkyl Phosphonium Salts” Meghan. F, Jackson. D, Srinivas D, Jeffrey. S, Jakob. M. Organic Letters, 2021, 23, 4548-4552.

20. “Genetic and Chemical Screening in Human Blood Serum Reveals Unique Antibacterial Targets and Compounds against Klebsiella pneumoniae” Brent S. W, Aaron M De J, Amelia BY G, Srinivas. D, Shawn F, Aline A F-C, Brian K C, Jakob M, Eric D B. Cell Report, 2020, 32 (3), 107927.

19. “A Halogen-Free Green High Energy Density Oxidizer from H-FOX” Srinivas. D and Shreeve, J. M. European Journal of Organic Chemistry, 2019, 20, 3142-3145.

18. “Taming of Tetranitroethane: A Promising Precursor to High Performance Energetic Ingredients” Ping. Y, Qiong. Y, Srinivas. D, and Shreeve. J. M. J. Mater. Chem. A, 2018, 6, 15815-15820.

17.“Hydrazide Salts of di-Picric Acid as Dense and Insensitive Energetic Materials” Devi. A., Srinivas. D., Ghule. V. D. Chemistry Select, 2018, 3, 4501-4504.

16.“A Safer Synthesis of 3,5-Bis(dinitromethyl)-1,2,4-triazole (BDT) and Its Mono and Di Salts: High-Performance Insensitive Energetic Materials” Srinivas. D and Shreeve, J. M. Propellants, Explosives, and Pyrotechnics, 2018, 43, 48–53.

15.“5-(Dinitromethyl)-3-(trinitromethyl)-1,2,4-triazole and Its Derivatives: A New Application of Oxidative Nitration Towards Gem-trinitro-based Energetic Materials” Srinivas. D, Zhang. J., Gregory H. I., Parrish, D. A., Shreeve, J. M. J. Mater. Chem. A, 2017, 5, 4785-4790.

14.“Nitramino- and dinitromethyl-substituted 1,2,4-triazole derivatives as high-performance energetic materials” Tang. Y., Srinivas. D, Imler. H. I., Parrish, D. A., Shreeve, J. M. Chem. Eur. J., 2017, 38, 9185–9191.

13.“From FOX-7 to H-FOX to Insensitive Energetic Materials with Hypergolic Properties” Srinivas. D, Mitchell, L. A., Parrish, D. A., Shreeve, J. M. Chem. Commun., 2016, 52, 7668-7671.

12."Energetic Salts Based on 3,5-Bis(dinitromethyl)-1,2,4-triazole Monoanion and Dianion: Controllable Preparation, Characterization, and High Performance" Srinivas. D, Zhang. J., Mitchell, L. A., Parrish, D. A., Shreeve, J. M. J. Am. Chem. Soc., 2016, 24, 7500–7503

11.“Bridged Bisnitramide-Substituted Furazan-based Energetic Materials” Zhang. J., Srinivas. D, Mitchell, L. A., Parrish, D. A., Shreeve, J. M. J. Mater. Chem. A, 2016, 4, 16961-16967.

10.“Synthesis of Nitrate Ester and Nitramine Derivatives of Polyfluoro Alkyl Compounds for High Energy Materials” Srinivas. D* and Ghule. V. D. RSC ADV., 2016, 6, 7712-7716.

9.“Study of thermal decomposition mechanisms and low‑level detection of explosives using pulsed photoacoustic technique” Yehya. F., Chaudhary. A. K., Srinivas. D., and Muralidharan. K. Appl. Phys. B., 2015, 121, 193-202.

8.“Molecular Design and Screening of Energetic Nitramine Derivatives” Devi. A., Sonal. D., Srinivas. D., Ghule. V. D. J. Mol. Model., 2015, 21, 298.

7.“Energetic Salts Prepared from Phenolate Derivatives” Srinivas. D., Ghule. V. D., Muralidharan. K. New J. Chem., 2014, 38, 3699-3707.

6.“Synthesis of nitrogen-rich imidazole, 1,2,4-triazole and tetrazole-based compounds”, Srinivas. D., Ghule. V. D., Muralidharan. K. RSC Adv., 2014, 4, 7041-7051.

5.“Energetic Monoanionic Salts of 3,5-Dinitropyridin-2-ol”, Ghule. V. D., Srinivas. D., Muralidharan. K. Asian J. Org. Chem. 2013, 8, 662-668.

4.“Tetraanionic nitrogen-rich tetrazole based energetic salts”, Srinivas. D., Ghule. V. D., Muralidharan. K, Jenkins. H. D. B. Chem. Asian J., 2013, 8, 1023-1028.

3.“Molecular design of amino-polynitroazole based high energy materials”, Ghule. V. D., Srinivas. D., Radhakrishnan. S., Jadhav. P. M., Tewari. S. P, J. Mol. Model., 2012, 18, 3013-3020.

2.“Computational study on energetic properties of nitro derivatives of furan substituted azoles”, Ghule. V. D., Srinivas. D., Radha krishnan. S., Jadhav. P. M., Tewari. S. P, Struct. Chem., 2012, 23, 749-754.

1.“Synthesis of Amino, Azido, Nitro and Nitrogen-rich Azole Substituted derivatives of 1H-Benzotriazole for High Energy Materials Applications”, Srinivas. D., Ghule. V. D., Tewari. S. P., Muralidharan. K, Chem. Eur. J., 2012, 18, 15031-15037.